Molarity Calculator

Calculate molarity, moles, and volume for solution concentration calculations

g/mol

What is Molarity?

Molarity (M) is a measure of the concentration of a solution, defined as the number of moles of solute dissolved per liter of solution. It is one of the most commonly used units of concentration in chemistry and is expressed in moles per liter (mol/L or M).

Molarity Formula:

M = n / V

M = (mass / MW) / V

  • M = Molarity (mol/L or M)
  • n = Number of moles of solute (mol)
  • V = Volume of solution (L)
  • mass = Mass of solute (g)
  • MW = Molecular weight (g/mol)

Dilution Formula (M₁V₁ = M₂V₂)

When diluting a stock solution, the number of moles remains constant. The dilution equation relates the initial and final concentrations and volumes:

M₁V₁ = M₂V₂

  • M₁ = Molarity of stock solution
  • V₁ = Volume of stock solution needed
  • M₂ = Molarity of diluted solution
  • V₂ = Final volume of diluted solution

Worked Examples

Example 1: Calculate Molarity from Mass

Problem: What is the molarity of a solution made by dissolving 5.844 g of NaCl (MW = 58.44 g/mol) in enough water to make 1000 mL of solution?

Step 1: Calculate moles
n = mass / MW = 5.844 g / 58.44 g/mol = 0.100 mol

Step 2: Convert volume to liters
V = 1000 mL × (1 L / 1000 mL) = 1.000 L

Step 3: Calculate molarity
M = n / V = 0.100 mol / 1.000 L = 0.100 M

Answer: 0.100 M NaCl

Example 2: Calculate Mass Needed

Problem: How many grams of NaCl (MW = 58.44 g/mol) are needed to prepare 250 mL of a 0.5 M solution?

Step 1: Convert volume to liters
V = 250 mL × (1 L / 1000 mL) = 0.250 L

Step 2: Calculate moles needed
n = M × V = 0.5 M × 0.250 L = 0.125 mol

Step 3: Calculate mass
mass = n × MW = 0.125 mol × 58.44 g/mol = 7.305 g

Answer: 7.305 g NaCl

Example 3: Dilution Calculation

Problem: How much of a 10 M stock solution is needed to make 100 mL of a 1 M solution?

Step 1: Use dilution formula
M₁V₁ = M₂V₂

Step 2: Solve for V₁
V₁ = (M₂ × V₂) / M₁ = (1 M × 100 mL) / 10 M = 10 mL

Step 3: Calculate diluent volume
Diluent = V₂ - V₁ = 100 mL - 10 mL = 90 mL

Answer: Add 10 mL of 10 M stock to 90 mL water

Common Laboratory Solutions

Solution Formula MW (g/mol) Typical Molarity Use
Sodium Chloride NaCl 58.44 0.9 M (physiological) Buffer, cell culture
Hydrochloric Acid HCl 36.46 1-6 M pH adjustment, digestion
Sodium Hydroxide NaOH 40.00 1-10 M pH adjustment, titration
Tris Buffer Tris-HCl 121.14 0.05-1 M Biological buffers
EDTA C₁₀H₁₆N₂O₈ 292.24 0.5 M Chelating agent
Glucose C₆H₁₂O₆ 180.16 5.5 mM (blood) Cell culture, metabolic

Best Practices for Solution Preparation

✓ Do's

  • Use analytical balance for accurate weighing (±0.0001 g)
  • Use volumetric flasks for final volume adjustments
  • Dissolve solute completely before adding to final volume
  • Label solutions with name, concentration, date, and preparer
  • Use deionized or distilled water for preparation
  • Store solutions properly (temperature, light sensitivity)

✗ Don'ts

  • Don't add water to concentrated acid (add acid to water)
  • Don't use graduated cylinders for final volume (use volumetric)
  • Don't leave solute undissolved when bringing to volume
  • Don't use expired or degraded chemicals
  • Don't pipette by mouth (always use pipette bulbs/pumps)
  • Don't prepare more solution than needed if it degrades

⚠️ Safety Reminders:

  • • Always wear appropriate PPE (lab coat, gloves, safety glasses)
  • • Work in fume hood when handling volatile or toxic substances
  • • Consult SDS (Safety Data Sheets) for hazard information
  • • Never add water to concentrated acids (exothermic reaction)
  • • Dispose of chemical waste according to regulations

Note: This calculator assumes ideal solutions and does not account for activity coefficients, temperature effects on volume, or non-ideal behavior. For precise analytical work or concentrated solutions, consult specialized resources and consider these factors. Always verify molecular weights from reliable sources such as NIST or chemical suppliers.

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